| Hint | Answer | % Correct |
|---|---|---|
| alkene => alkane conditions: (1) ____ catalyst | nickel | 100%
|
| or ____ catalyst under lab conditions | platinum | 100%
|
| alkene => halogenoalkane: requires the halogen and ____ light | UV/ultraviolet | 100%
|
| (2) ____ degrees C temperature | 300 | 50%
|
| (3) ____ atm pressure | 5 | 50%
|
| keep below ____ degrees C | 5 | 50%
|
| keep below ____ degrees C | 55 | 50%
|
| acyl chloride => ester: react with ____ at room temperature | alcohol | 50%
|
| if ammonium is present, ____ will be liberated | ammonia | 50%
|
| gives a ____ ring with an R group | benzene | 50%
|
| gives a ____ ring with a COR group | benzene | 50%
|
| ammonia gas turns damp red litmus paper ____ | blue | 50%
|
| react ____ nitric and ____ sulfuric acid to form the NO2+ electrophile | concentrated | 50%
|
| acyl chloride => primary amide: react with ____ at room temperature | concentrated ammonia | 50%
|
| compound containing a relatively reactive benzene ring, usually phenol or phenylamine | coupling agent | 50%
|
| CN group attached to the same carbon atom as an OH group | cyanohydrin/hydroxynitrile | 50%
|
| solubility of silver halides in ammonia ____ down the group | decreases | 50%
|
| and ____ alloy | Devarda's | 50%
|
| Ba2+ flame test colour | green | 50%
|
| primary alcohol => halogenoalkane: reflux with (1) sodium ____ | halide | 50%
|
| alkene => halogenoalkane: react alkene with ____ | hydrogen halide | 50%
|
| halogenoalkane => primary alcohol: reflux with sodium ____ | hydroxide | 50%
|
| K+ flame test colour | lilac | 50%
|
| carbonate ion test: add dilute acid and bubble through ____ | limewater | 50%
|
| Pb2+ test: react with ____ | potassium iodide | 50%
|
| test for hydroxide ions: turns ____ litmus paper blue | red | 50%
|
| Tollen's reagent: warm in a test tube, positive result is ____ forms | silver mirror | 50%
|
| test for ammonium ions: heat with ____ | sodium hydroxide | 50%
|
| test for nitrate: heat with ____ | sodium hydroxide | 50%
|
| aldehyde => primary alcohol: react with ____ | sodium tetrahydridoborate | 50%
|
| bromine water decolorises in the presence of ____ | unsaturation | 50%
|
| Na+ flame test colour | yellow | 50%
|
| (2) ____ degrees C temperature | 150 | 0%
|
| primary alcohol => aldehyde: reflux with ____ | acidified potassium dichromate | 0%
|
| aldehyde => carboxylic acid: reflux with ____ | acidified potassium dichromate | 0%
|
| primary alcohol => alkene: (1) ____ catalyst | alumina | 0%
|
| Friedl Crafts alkylation: reflux with RCl and ____ | aluminium (III) chloride | 0%
|
| Friedl Crafts acylation: reflux with ROCl or (RCO)2O and ____ | aluminium (III) chloride | 0%
|
| benzene => chlorobenzene: react with chlorine and ____ | aluminium (III) chloride | 0%
|
| positive result: ____ gas liberated | ammonia | 0%
|
| and ____ | aqueous barium chloride | 0%
|
| (1) dissolve ____ | aromatic amine | 0%
|
| aqueous NaOH + copper 2+ ions precipitate | blue | 0%
|
| Cu2+ flame test colour | blue green | 0%
|
| Fehling's test: warm with Fehling's A and B, positive result is blue solution to ____ | brick red precipitate | 0%
|
| Li+ flame test colour | bright red | 0%
|
| positive result is a ____ | bright yellow precipitate | 0%
|
| halogenoalkane => amine: heat in a sealed tube with ____ | concentrated ammonia | 0%
|
| benzene => benzenesulfonic acid: reflux with ____ | concentrated H2SO4 | 0%
|
| (2) ____ | concentrated hydrochloric acid | 0%
|
| alkene => primary alcohol: react with water and ____ | concentrated sulfuric acid | 0%
|
| (2) ____ | concentrated sulfuric acid | 0%
|
| carboxylic acid => ester: react with alcohol in the presence of ____ | concentrated sulfuric acid | 0%
|
| coupling reaction: diazonium compound reacts with a ____ | coupling agent | 0%
|
| formation of a diazonium salt or ____ | diazotisation | 0%
|
| nitrile => carboxylic acid: reflux with ____ and water | dilute hydrochloric acid | 0%
|
| in ____ | dilute hydrochloric acid | 0%
|
| aqueous NaOH + iron 2+ ions precipitate | green | 0%
|
| aqueous NaOH + chromium 3+ ions precipitate | green | 0%
|
| sulfate ion test: add dilute ____ | hydrochloric acid | 0%
|
| benzene => bromobenzene: react with bromine and ____ | iron (III) bromide | 0%
|
| phenol test: add neutral ____ | iron (III) chloride | 0%
|
| aldehyde => cyanohydrin: react with HCN or more safely ____ | KCN | 0%
|
| if present, limewater turns ____ | milky | 0%
|
| ester => carboxylic acid: hydrolyse with ____ acid or alkali | moderately concentrated | 0%
|
| benzene => nitrobenzene: ____ mixture forms first | nitrating | 0%
|
| test for halide ions: react with ____ acid | nitric | 0%
|
| CN group attached to a carbon atom | nitrile | 0%
|
| unstable ____ forms and reacts with the NH2 group | nitrous acid | 0%
|
| Mg2+ + excess sulfuric acid | no change | 0%
|
| Ca2+ + ammonia solution | no change | 0%
|
| Sr2+ + ammonia solution | no change | 0%
|
| Ba2+ + excess sodium hydroxide | no change | 0%
|
| Ba2+ + ammonia solution | no change | 0%
|
| aqueous NaOH + iron 3+ ions precipitate | orange-brown | 0%
|
| Ca2+ flame test colour | orange red | 0%
|
| white precipitate for Cl-, cream for Br-, ____ for I- | pale yellow | 0%
|
| acyl chloride => secondary amide: acylation with a ____ | primary amine | 0%
|
| and ____ | silver nitrate | 0%
|
| Ca2+ + excess sulfuric acid | slight white precipitate | 0%
|
| Sr2+ + excess sodium hydroxide | slight white precipitate | 0%
|
| halogenoalkane => nitrile: reflux with ____ in ethanol | sodium cyanide | 0%
|
| Zn2+ test: white precipitate with ____ that dissolves in excess ____ | sodium hydroxide | 0%
|
| (2) add cold ____ | sodium nitrate (III) | 0%
|
| the electrophile here is the ____ ion which is SO2OH+ (formed by losing 1 OH group) | sulfonium | 0%
|
| carboxylic acid => acyl chloride: reflux with ____ | thionyl chloride | 0%
|
| nitrobenzene => phenylamine: reflux with (1) ____ | tin | 0%
|
| positive result: turns from yellow to ____ | violet | 0%
|
| Mg2+ + excess sodium hydroxide solution | white precipitate | 0%
|
| Mg2+ + ammonia solution | white precipitate | 0%
|
| Ca2+ + sodium hydroxide | white precipitate | 0%
|
| Sr2+ + excess sulfuric acid | white precipitate | 0%
|
| Ba2+ + excess sulfuric acid | white precipitate | 0%
|
| positive result: ____ | white precipitate | 0%
|