Use clues to identify location. The clues are: (1) the capital (see caveats) (2) the continent where the answer is located; and (3) an indication of whether the answer is a sovereign state.
End of set.
Source: Wikipedia List of national capitals.
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For sovereign states with multiple capitals, only one is given, with precedence as follows. 1. The de jure or constitutional capital, if one exists; else 2. The official or declared capital, if one has been designated; else 3. The executive or administrative capital.
For sovereign states with no official capital, the de facto capital is given.
For non-sovereign states, the de facto capital is given.
Evil aliens have decided to kill everyone on Earth! Fortunately, they've given you two minutes to save as many as you can. All you have to do is name a country to save everyone in it.