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Answer
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Designed to be located (almost) equally between its two biggest cities - Melbourne and Sydney.
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Canberra
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After the destruction of much of Belize City, this city was constructed further inland at a less weather-prone site.
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Belmopan
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Formed when the British 'Bechuanaland Protectorate' gained independence in 1966, with existing towns Mafeking, Lobatse and Gaberones seen as inadequate capitals.
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Gaborone
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First conceived more than a hundred years before being built, the city became the capital succeeding Rio de Janeiro in 1960.
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Brasilia
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Despite being first colonised only in 1886, this Oceanian village (and its island nation) changed hands from Spain to Germany, then Japan and finally the USA before gaining its independence.
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Palikir
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Despite many of the country's political infrastructure remaining in former capital Abidjan, this has legally been the capital since 1983.
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Yamoussoukro
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Formerly named Akmola, the city was planned and then completely transformed after the fall of the Soviet Union.
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Astana
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Originally a colonial village ruled from Saint-Louis, Senegal. After securing independence, it was designed initially to accommodate 15,000 people, but now has a population of over 1 million.
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Nouakchott
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Answer
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Founded by the military government to be located more centrally, moving from Yangon in 2005.
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Naypyidaw
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Moved to be independent from the three major ethnic groups - the Igbo, Yoruba, and Hausa-Fulani people. Former capital Lagos.
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Abuja
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Finally deciding on an area northeast of Rawalpindi, the city's location was found to be optimal for climate, logistics, and proximity to the country's military base of operations.
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Islamabad
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Replacing Koror City in 2006, with construction partially funded by Taiwan.
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Ngerulmud
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After the fall of the Inca Empire, the site was chosen as a capital due to its cooler climate, fertile land and proximity to coastline which could become a port. For many years the country remained a Spanish Viceroyalty before becoming independent.
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Lima
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Despite many countries leaving their embassies and offices in its former capital Dar Es Salaam, this has been the capital since 1996.
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Dodoma
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On land donated by Maryland and Virginia on the Potomac River, in a location chosen by George Washington.
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Washington D.C.
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Good quiz, though—nominated.