| Hint | Answer | % Correct |
|---|---|---|
| Catalysts can be changed ____ but not chemically - take some part in the reaction but are regenerated | Physically | 38%
|
| Molecule with a positive carbon atom | Carbocation | 25%
|
| Substance that speeds up reaction but can be recovered chemically unchanged after | Catalyst | 25%
|
| DF5 Where a larger molecule is made into smaller molecules | Cracking | 25%
|
| Boiling points ____ as number of carbons increases | Increase | 25%
|
| Double bond contains one of these, and one ____ bond | Pi | 25%
|
| When solid catalyst used, reaction occurs on ____ of solid | Surface | 25%
|
| DF6 Compound with C=C double bond | Alkene | 13%
|
| Reactants and catalyst are in the ____ state | Aqueous | 13%
|
| Positive ions/molecules with partial positive charge are ____ to this region | Attracted | 13%
|
| New ____ form between the reactants, held close together on catalyst surface | Bonds | 13%
|
| Carbocation is positive and reacts with ____ ion - pair of electrons move from it and bond to positively charged carbon | Bromide | 13%
|
| Convert them into less harmful gases like water vapour or ____ ____ | Carbon dioxide | 13%
|
| Process of speeding up chemical reaction using catalyst | Catalysis | 13%
|
| General formula | CnH2n | 13%
|
| Name of this reaction | Electrophilic addition | 13%
|
| Where are the products of cracking separated | Fractionating column | 13%
|
| When reactants and catalyst are in different physical states | Heterogeneous | 13%
|
| In ____ catalysis, poison molecules adsorbed more strongly than reactants | Heterogeneous | 13%
|
| Addition of water to an alkene | Hydration | 13%
|
| Molecules with the same molecular formula but different arrangements of atoms | Isomers | 13%
|
| Br molecule becomes ____ as it approaches the alkene | Polarised | 13%
|
| Fe (3+) then ____ by the iodide, forming an I2 molecule | Reduced | 13%
|
| Catalysts need a large ____ ____. Often used in a finely divided form or as a fine mesh | Surface area | 13%
|
| An organic compound that has a double or triple bond between carbon atoms | Unsaturated | 13%
|
| Bonds in reactant molecules are therefore ____ and break | Weakened | 13%
|
| What catalyst is used | Zeolite | 13%
|
| Nickel also works. Must be finely powdered. Temperature ____C and pressure ____atm | 150 5 | 0%
|
| Poison molecules block ____ ____ causing the catalyst to become inactive | Active sites | 0%
|
| Reaction where this occurs with no byproducts | Addition polymerisation | 0%
|
| Reactants form bonds with atoms on catalyst surface - ____ onto surface | Adsorbed | 0%
|
| Molecule with -OH functional group | Alcohol | 0%
|
| This reaction will produce a ____ - but bromine water still decolorises | Bromoalcohol | 0%
|
| The positive bromine atom can now behave as electrophile. Bonds with alkene to form ____ | Carbocation | 0%
|
| Ethene also reacts with hydrogen. Requires ____ to break strong H-H bond | Catalyst | 0%
|
| What does this happen in | Catalytic converters | 0%
|
| Same molecular formula, but the longest hydrocarbon chain is not the same | Chain isomerism | 0%
|
| Carbon from the decomposition of hydrocarbon molecules | Coke | 0%
|
| When more than one monomer is incorporated into the final polymer | Copolymerisation | 0%
|
| When ethene gas is bubbled through bromine, Br becomes ____ | Decolorised | 0%
|
| The four electrons in the ethene double bond give the region between the carbon atoms a higher than normal ____ of negative charge | Density | 0%
|
| In laboratory - ethene converted to ethanol by adding sulfuric acid then ____ with water | Diluting | 0%
|
| Two highest priority groups are on opposite sides of the double bond | E isomer | 0%
|
| These ____ react by accepting a pair of electrons from the C=C double bond | Electrophiles | 0%
|
| Average bond ____ to break the bond in ethene is +270kJ/mol | Enthalpy | 0%
|
| Used in industrial manufacture of | Ethanol | 0%
|
| H-O-SO3H reacts with ethene to form | Ethyl hydrogensulfate | 0%
|
| Energy released from burning coke heats catalyst, and energy transferred to ____ | Feedstock | 0%
|
| The mixture in the reactor is a moving ____ ____ where solid particles flow like a liquid | Fluidised bed | 0%
|
| Same molecular formula, different functional group | Functional group isomerism | 0%
|
| When reactants and catalysts are in same physical state | Homogenous catalysis | 0%
|
| Catalyst goes into regenerator, where the coke is burn off by ____ ____ | Hot air | 0%
|
| The ____ will react with a carbon first | Hydrogen | 0%
|
| Reaction of ethene with hydrogen | Hydrogenation | 0%
|
| Ethene also readily reacts at room temperature with a solution of ____ ____ | Hydrogen bromide | 0%
|
| Two electrons are arranged between the atoms in an area of ____ ____ ____ | Increased electron density | 0%
|
| Catalyst in reaction between peroxidisulfate (2-) and iodide (I-) = ____ (2+) | Iron/Fe | 0%
|
| This is why ____ petrol can't be used in cars fitted with catalytic converter (lead strongly adsorbed to catalyst) | Leaded | 0%
|
| Consists of two areas of ____ ____, one above and one below the line of the atoms | Negative charge | 0%
|
| Both ions are ____ charged so the reaction takes a lot of energy | Negatively | 0%
|
| If feedstock for Haber process contains sulfur compounds, these must be removed to prevent poisoning of ____ catalyst | Nickel/Ni | 0%
|
| Can also shake alkene with bromine water. Water molecules act as ____ so compete with bromide ions | Nucleophiles | 0%
|
| It first ____ S2O8 to form 2 sulfate (2-) ions and 2 Fe (3+) ions | Oxidises | 0%
|
| Occurs at high temperature, high pressure, and in presence of catalyst (____ ____ adsorbed onto solid ____) | Phosphoric acid silica | 0%
|
| Stereoisomers exist because you can't rotate one end of the molecule due to the ____ bond | Pi | 0%
|
| If ____ catalyst used, can take place under standard laboratory conditions | Platinum | 0%
|
| When a catalyst is blocked from being able to function properly | Poison | 0%
|
| Catalytic converters help reduce toxic ____ released into air | Pollutants | 0%
|
| DF7 A long molecule made up from many small monomers | Polymer | 0%
|
| Sometimes supported on ____ material to increase SA and prevent crumbling | Porous | 0%
|
| Same molecular formula, functional group in a different place | Position isomerism | 0%
|
| Weakens bonds to catalyst surface and ____ molecules are released | Product | 0%
|
| Logically deciding movement of electrons using ideas like bond polarity and charges | Reaction mechanism | 0%
|
| The catalyst needs to be ____ when this forms on the catalyst surface | Regenerated | 0%
|
| When the surface of a catalyst is cleaned and usable again | Regeneration | 0%
|
| Electrons in bromine ____ by alkene electrons and pushed back along molecule | Repelled | 0%
|
| What is the reactor called | Riser reactor | 0%
|
| It's called this because of the overlap of ____ orbitals | S | 0%
|
| Used to ____ fats and oils | Saturate | 0%
|
| After the riser reactor, the mixture passes into a ____ | Separator | 0%
|
| Single bond | Sigma | 0%
|
| What are the hot vaporised hydrocarbons and catalyst forced up by | Steam | 0%
|
| Same molecular formula, same structural formula but differ in how atoms arranged in space | Stereoisomerism | 0%
|
| Same molecular formula, atoms bonded together in different order | Structural isomerism | 0%
|
| Use expensive metals - cheaper ones more vulnerable to poisoning by trace amounts of ____ ____ | Sulfur dioxide | 0%
|
| This reacts with water to form ethanol and ____ acid | Sulfuric | 0%
|
| DF9 Shape of methane | Tetrahedral | 0%
|
| Many heterogeneous catalysts are | Transition metals | 0%
|
| Cracking can occur ____ additional heating | Without | 0%
|
| Two highest priority groups are on the same side of the double bond | Z isomer | 0%
|