Alkynes (Organic Chemistry) - Statistics

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  • The average score is 11 of 40
Answer Stats
Hint Answer % Correct
An alkyne consists of one _____ and two __ Bonds Sigma, Pi
100%
The bond angle of an alkyne is ___ degrees 180
67%
The hybridization of alkynes is __ sp
67%
pH of terminal alkynes 25
33%
What is a vicinal dihalide? Two halogens attached to _______ carbon atoms adjacent
33%
The reaction yields an ________ instead of a ketone aldehyde
33%
1 equivalent of X2 gives an ______ (E being major product) alkene
33%
What starting material is used to make an alkyne? alkyl dihalide
33%
Rate = k [______] [__]^2 alkyne, HX
33%
In prescence of peroxides, HBr undergoes ____-__________ addition anti markovnikov
33%
Hydroboration-Oxidation of alkynes proceeds via ____-___________ addition anti Markovnikov
33%
Why can't you use Na and NH3 (l) to reduce a terminal alkyne to an alkene? The alkyne will be ___________ deprotonated
33%
What reaction mechanism is used when forming an alkyne from an alkyl dihalide? E2
33%
The intermediate takes the trans position because _____ repulsion electron
33%
proton transfers and replacement of mercury yields an ____ Enol
33%
The reaction gives a mixture of _ and _ alkenes E,Z
33%
Poisoned catalysts work by catalyzing the _____ step but not the ______ step first, second
33%
With xs HX, X adds via Markovnikov addition and makes a _______ dihalide geminal
33%
`The three reactants needed for this reaction are _____, ___, _____ HgSO4, H2O, H2SO4
33%
It will then tautomerize into a ______ Ketone
33%
In hydrohalogenation of alkynes with one equivalent of HX, X adds via ___________ addition Markovnikov
33%
hydration of alkynes proceeds via __________ addition Markovnikov
33%
A key intermediate being the _________ ion Mercurium
33%
What base is commonly used to deprotonate an alkyne? NaNH2
33%
What reagents are used to get a trans alkene from an internal alkyne? Na, NH3 (l)
33%
Water will carry out a ____________ ______ nucleophilic attack
33%
Reduction of alkynes is performed with H2 and a platinum, nickel or a palladium catalyst. What type of catalyst is used when you want the reaction to stop at a cis alkene? Poisoned catalyst
33%
What does geminal dihalide mean? Two halogens attached to the ____ carbon atom same
33%
First (1)______ donates an electron, forming the radical intermediate, the anion takes a proton from (2)_______, then (1) _____ donates another electron to form an anion that finally takes another proton from (2) _______ to finish the reaction. sodium, ammonia
33%
The mechanism for hydrohalogenation is ___molecular ter
33%
Ozonolysis yields __________ ____ and/or _____ ______ when it is a terminal alkyne carboxylic acids carbon dioxide
0%
The first step of alkylating an alkyne is ____________ with NaNH2 deprotonation
0%
How to reduce a terminal alkyne to alkene? H2, Poisoned catalyst
0%
To go from an alkyl dihalide use xs_____, ___ (l), and H2O afterwards NaNH2, NH3
0%
What is the P-2 catalyst (another poisoned catalyst) Ni2B
0%
What reagents make up "Lindlar's catalyst" Pd, CaCO3, PbO2
0%
This is a three step reaction with a _______ ____ intermediate radical anion
0%
Then, the alkynide ion can be used in an ___ reaction with RX SN2
0%
xs X2 yields a __________ tetrahalide
0%
Halogenation of alkynes needs __ as a reactant X2
0%
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