| Hint | Answer | % Correct |
|---|---|---|
| An alkyne consists of one _____ and two __ Bonds | Sigma, Pi | 100%
|
| The bond angle of an alkyne is ___ degrees | 180 | 67%
|
| The hybridization of alkynes is __ | sp | 67%
|
| pH of terminal alkynes | 25 | 33%
|
| What is a vicinal dihalide? Two halogens attached to _______ carbon atoms | adjacent | 33%
|
| The reaction yields an ________ instead of a ketone | aldehyde | 33%
|
| 1 equivalent of X2 gives an ______ (E being major product) | alkene | 33%
|
| What starting material is used to make an alkyne? | alkyl dihalide | 33%
|
| Rate = k [______] [__]^2 | alkyne, HX | 33%
|
| In prescence of peroxides, HBr undergoes ____-__________ addition | anti markovnikov | 33%
|
| Hydroboration-Oxidation of alkynes proceeds via ____-___________ addition | anti Markovnikov | 33%
|
| Why can't you use Na and NH3 (l) to reduce a terminal alkyne to an alkene? The alkyne will be ___________ | deprotonated | 33%
|
| What reaction mechanism is used when forming an alkyne from an alkyl dihalide? | E2 | 33%
|
| The intermediate takes the trans position because _____ repulsion | electron | 33%
|
| proton transfers and replacement of mercury yields an ____ | Enol | 33%
|
| The reaction gives a mixture of _ and _ alkenes | E,Z | 33%
|
| Poisoned catalysts work by catalyzing the _____ step but not the ______ step | first, second | 33%
|
| With xs HX, X adds via Markovnikov addition and makes a _______ dihalide | geminal | 33%
|
| `The three reactants needed for this reaction are _____, ___, _____ | HgSO4, H2O, H2SO4 | 33%
|
| It will then tautomerize into a ______ | Ketone | 33%
|
| In hydrohalogenation of alkynes with one equivalent of HX, X adds via ___________ addition | Markovnikov | 33%
|
| hydration of alkynes proceeds via __________ addition | Markovnikov | 33%
|
| A key intermediate being the _________ ion | Mercurium | 33%
|
| What base is commonly used to deprotonate an alkyne? | NaNH2 | 33%
|
| What reagents are used to get a trans alkene from an internal alkyne? | Na, NH3 (l) | 33%
|
| Water will carry out a ____________ ______ | nucleophilic attack | 33%
|
| Reduction of alkynes is performed with H2 and a platinum, nickel or a palladium catalyst. What type of catalyst is used when you want the reaction to stop at a cis alkene? | Poisoned catalyst | 33%
|
| What does geminal dihalide mean? Two halogens attached to the ____ carbon atom | same | 33%
|
| First (1)______ donates an electron, forming the radical intermediate, the anion takes a proton from (2)_______, then (1) _____ donates another electron to form an anion that finally takes another proton from (2) _______ to finish the reaction. | sodium, ammonia | 33%
|
| The mechanism for hydrohalogenation is ___molecular | ter | 33%
|
| Ozonolysis yields __________ ____ and/or _____ ______ when it is a terminal alkyne | carboxylic acids carbon dioxide | 0%
|
| The first step of alkylating an alkyne is ____________ with NaNH2 | deprotonation | 0%
|
| How to reduce a terminal alkyne to alkene? | H2, Poisoned catalyst | 0%
|
| To go from an alkyl dihalide use xs_____, ___ (l), and H2O afterwards | NaNH2, NH3 | 0%
|
| What is the P-2 catalyst (another poisoned catalyst) | Ni2B | 0%
|
| What reagents make up "Lindlar's catalyst" | Pd, CaCO3, PbO2 | 0%
|
| This is a three step reaction with a _______ ____ intermediate | radical anion | 0%
|
| Then, the alkynide ion can be used in an ___ reaction with RX | SN2 | 0%
|
| xs X2 yields a __________ | tetrahalide | 0%
|
| Halogenation of alkynes needs __ as a reactant | X2 | 0%
|